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Understanding Calcium Hypochlorite Through Its Material Safety Data Sheet (MSDS)

Calcium Hypochlorite, also known as chlorine powder or chlorin, has the chemical formula Ca(OCl)₂. It is a widely used disinfectant in daily life. Let Dong A guide you through this product based on its Material Safety Data Sheet (MSDS).

SECTION I: IDENTIFICATION OF THE SUBSTANCE AND SUPPLIER

1. Substance Information

Product Name

Common Name

Trade Name

CAS No

UN

No

EC No

HMIS Classification (USA)

Calcium Hypochlorite

Calcium Hypochlorite 

Chlorine  

7778-54-3 

 

1748 

231-908-7 

Health Hazard: 3

Flammability: 0

Reactivity: 2

Personal Protection: J

2. Recommended Uses and Restrictions

Used for disinfection of drinking water and swimming pools. Calcium Hypochlorite is also used in toilet cleaners, household disinfectants, and for controlling moss and algae.

3. Manufacturer Information

Dong A Chemical Joint Stock Company  
Area 9, Phu Ninh Commune, Phu Tho Province, Vietnam  
Tel: +84 210 652 3333  
Email: kinhdoanh@dongachem.vn

4. Emergency Contact

Dong A Chemical Joint Stock Company  
Tel: +84 210 652 3333  
Email: kinhdoanh@dongachem.vn

SECTION II: HAZARD IDENTIFICATION

1. GHS Classification

1.1 Physical Hazards

calcium-hypochlorite-hs-2828100

1.2 Health Hazards

calcium-hypochlorite-hs-2828100-1

2. Hazard Statements

  • H272: May intensify fire; oxidizer
  • H302: Harmful if swallowed
  • H314: Causes severe skin burns and eye damage
  • H400: Very toxic to aquatic life

3. Precautionary Statements

  • P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
  • P220: Keep away from clothing and combustible materials
  • P221: Take precautions to avoid mixing with combustibles
  • P260: Do not breathe dust/fume/gas/mist/vapors
  • P264: Wash thoroughly after handling
  • P270: Do not eat, drink or smoke when using this product
  • P273: Avoid release to the environment
  • P280: Wear protective gloves/clothing/eye/face protection
  • P284: Wear respiratory protection
  • P301+P312: IF SWALLOWED: Call a poison center/doctor immediately
  • P301+P330+P331: Rinse mouth. Do NOT induce vomiting
  • P303+P361+P353: IF ON SKIN: Remove contaminated clothing. Rinse skin with water
  • P304+P340: IF INHALED: Move to fresh air
  • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes
  • P310: Immediately call a poison center/doctor
  • P321: Specific treatment required
  • P330: Rinse mouth
  • P363: Wash contaminated clothing before reuse
  • P370+P378: In case of fire: Use dry powder extinguisher
  • P391: Collect spillage
  • P405: Store locked up
  • P501: Dispose of contents/container in accordance with regulations

4. Other Hazards

No additional information available.

SECTION III: COMPOSITION / INFORMATION ON INGREDIENTS

Component

CAS No

Chemical Formula

Content (%

Calcium Hypochlorite 

7778-54-3  

Ca(OCl)2≥ 65 %

SECTION IV: FIRST AID MEASURES

1. Description of First Aid Measures

  • Eye Contact: Rinse immediately with water for at least 15 minutes. Seek medical attention.
  • Inhalation: Move to fresh air, keep at rest, seek medical attention.
  • Skin Contact: Remove contaminated clothing, rinse thoroughly with water.
  • Ingestion: Do not induce vomiting. Seek immediate medical attention.

2. Symptoms and Effects

Not classified as carcinogenic (OSHA, ACGIH). Not mutagenic or toxic to reproduction. Harmful to lungs and mucous membranes.

3. Medical Attention

Treat symptomatically under physician guidance.

SECTION V: FIRE-FIGHTING MEASURES

 Flammability

Hazard

Extinguishing Media

Protective Equipment

Special Hazards

Non-flammable 

Strong oxidizer, may intensify fire

 

Water spray (DO NOT use CO₂ or ammonium-based extinguishers)

 

Wear full protective gear and respirator

 

May accelerate combustion under heat

 

SECTION VI: ACCIDENTAL RELEASE MEASURES

  • Evacuate area and isolate hazard zone
  • Avoid contact and inhalation
  • Prevent entry into drains and waterways
  • Use absorbent materials (sand, soil)
  • Notify authorities if uncontrolled

SECTION VII: HANDLING AND STORAGE

Handling

  • Avoid inhalation and contact
  • Keep away from ignition sources
  • Follow operational procedures strictly

Storage

  • Store in a well-ventilated, cool, dry area
  • Keep away from sunlight and incompatible materials
  • Keep containers tightly closed

SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTION

  • Eye Protection: Safety goggles
  • Skin Protection: Protective clothing
  • Hand Protection: Chemical-resistant gloves
  • Foot Protection: Safety boots
  • Respiratory Protection: Suitable respirator
  • Prefer certified PPE (e.g., 3M)

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES

Appearance: powder/granules

Odor: Chlorine-like

Color:  White or off-white 

Melting Point: 100°C 

Odor: Chlorine-like

Flash Point (°C): No data available 

Vapor Pressure (mm Hg) at standard temperature and pressure: No data available

Auto-ignition Temperature (°C): No data available

Vapor Density (Air = 1) at standard temperature and pressure: No data available

Upper Flammability Limit (% by volume in air): No data available

Solubility: Soluble in water

Lower Flammability Limit (% by volume in air): No data available

Moisture Content (%): ≤ 10%

Evaporation Rate: No data available

Density (kg/m³): 2,350 at 20°C

Molecular Weight: 142.99 g/mol

SECTION X: STABILITY AND REACTIVITY

  • Decomposes rapidly in air and under heat (~177°C)
  • Strong oxidizer
  • Reacts with acids releasing chlorine gas
  • Reacts with ammonium compounds → explosion risk
  • Incompatible with water, organics, flammable materials

SECTION XI: TOXICOLOGICAL INFORMATION

  • Routes: Skin, eyes, inhalation, ingestion
  • Effects: Burns, eye damage, lung irritation
  • LD50 (oral, rat): 850 mg/kg
  • Not classified as carcinogenic

SECTION XII: ECOLOGICAL INFORMATION

  • Highly toxic to aquatic organisms
  • May cause environmental pollution if released
  • Not biodegradable by bacteria

SECTION XIII: DISPOSAL CONSIDERATIONS

Dispose of in accordance with hazardous waste regulations (Circular No. 02/2022/TT-BTNMT).

SECTION XIV: TRANSPORT INFORMATION

calcium-hypochlorite-hs-2828100-2

SECTION XV: REGULATORY INFORMATION

Complies with Vietnamese chemical laws and regulations, including:

  • Law on Chemicals No. 69/2025/QH15
  • Decrees 24/2026, 25/2026, 26/2026
  • Circulars 01/2026/TT-BCT, 02/2026/TT-BCT
  • Decree 34/2024/NĐ-CP on dangerous goods transportation

CONCLUSION

The above information summarizes the MSDS of Calcium Hypochlorite. We hope this document provides useful insights to help you handle and use the product safely and effectively.

For further information, please contact: Tel/WhatsApp/Viber/Zalo: +84 342 597 726

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